Ricercatore
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c/o Dip. Chimica Università di Roma “La Sapienza” P.le A. Moro 5, 00185 Roma |
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+39 06 49913396 | ||
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+39 06 49913629 | ||
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francesca.dacunzo@cnr.it | ||
Competenze
- Sintesi di monomeri e polimeri.
- Studio di reazioni enzimatiche e biomimetiche.
Attività di Ricerca
- Sintesi di nuovi monomeri per l’ottenimento di polimeri funzionali rispondenti a stimuli multipli, quali luce, temperatura, pH.
- Polimerizzazioni radicaliche controllate (RAFT).
- Sintesi di nuovi inibitori dell’enzima Carbonilriduttasi.
Pubblicazioni recenti / significative
- Nardi, F. D’Acunzo, M. Clemente, G. Proietti, P. Gentili “A first study on copolymers of a methacrylate containing the 2-(hydroxyimino)aldehyde group and OEGMA. RAFT polymerization and assessment of thermal and photoresponsive polymer behavior.” Polymer Chemistry, DOI: 10.1039/C7PY00975E (2017).
- D’Acunzo, P. Gentili, G. Masci, O. Ursini “Towards controlled cationic polymer growth from inorganic oxide defects: Directing the mechanism of polystyrene grafting from γ-irradiated silica” Polymer (United Kingdom) 55(20), 5043-5049, (2014).
- D’Acunzo, C. Galli, P. Gentili, F. Sergi “Mechanistic and steric issues in the oxidation of phenolic and non-phenolic compounds by laccase or laccase-mediator systems. the case of bifunctional substrates” New Journal of Chemistry 30(4), 583-591, (2006).
- D’Acunzo, C. Galli “First evidence of catalytic mediation by phenolic compounds in the laccase-induced oxidation of lignin models” European Journal of Biochemistry 270(17), 3634-3640, (2003).
- F. D’Acunzo, TQ Le, J. Kohn “Alternating multiblock amphiphilic copolymers of PEG and tyrosine-derived diphenols. 2. Self-assembly in aqueous solution and at hydrophobic surfaces” Macromolecules 35(25), 9366-9371, (2002).